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- Newsgroups: sci.misc
- Path: sparky!uunet!utcsri!helios.physics.utoronto.ca!alchemy.chem.utoronto.ca!mroussel
- From: mroussel@alchemy.chem.utoronto.ca (Marc Roussel)
- Subject: Re: Salt and soda pop
- Message-ID: <1992Aug27.163348.2105@alchemy.chem.utoronto.ca>
- Organization: Department of Chemistry, University of Toronto
- References: <17hqh4INNsvb@darkstar.UCSC.EDU> <1992Aug27.094131.1264@guvax.georgetown.edu>
- Date: Thu, 27 Aug 1992 16:33:48 GMT
- Lines: 35
-
- In article <1992Aug27.094131.1264@guvax.georgetown.edu>
- cfhammer@guvax.georgetown.edu writes:
- >In article <17hqh4INNsvb@darkstar.UCSC.EDU>,
- > haynes@cats.ucsc.edu (Jim Haynes) writes:
- >> Why is it that adding table salt to soda pop causes foaming? What's
- >> the chemical reaction (or is it all physical)?
- >
- >i would imagine that crystals added to a solution supercharged with
- >gas would provide a great source of cavitation nuclei (minute cracks
- >from which bubbles would grow due to vapor pressure differences
- >overcoming the surface tension at the gas-liquid interface).
- >
- >you can test this 'physical' theory by tossing sand, sugar, or
- >or whatever into some soda.
-
- There are two possible ways to explain this phenomenon:
-
- 1) The increased ionic strength of the solution due to the
- dissolving salt is making the gas less soluble.
- 2) The salt is providing nucleation loci (as suggested by
- Jim).
-
- If (1) were the case, this would only work with soluble substances
- and the effect would depend on the rate of dissolution; if (2), any
- granular solid that sinks in pop will produce the effect. In either
- case, sand is an ideal test substance (again, as Jim suggested). I did
- the experiment with sand a few years ago and got essentially the same
- result as with salt. Added to the observation that the salt doesn't
- visibly dissolve in the time required for the reaction to take place, I
- conclude that only (2) is important, i.e. that in this case, as in many
- others, the effect is not strictly thermodynamic in origin and has a
- substantial kinetic component.
-
- Marc R. Roussel
- mroussel@alchemy.chem.utoronto.ca
-