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- Newsgroups: sci.geo.fluids
- Path: sparky!uunet!stanford.edu!ames!nsisrv!hyperion.gsfc.nasa.gov!hannegan
- From: hannegan@hyperion.gsfc.nasa.gov (Bryan Hannegan)
- Subject: Back of the envelope calculations of oceanic CO2
- Message-ID: <1992Nov17.003417.10675@nsisrv.gsfc.nasa.gov>
- Sender: usenet@nsisrv.gsfc.nasa.gov (Usenet)
- Nntp-Posting-Host: hyperion.gsfc.nasa.gov
- Organization: Code 916, NASA Goddard Space Flight Center
- Date: Tue, 17 Nov 1992 00:34:17 GMT
- Lines: 38
-
- Newsgroups: sci.geo.fluids,sci.environment
- Subject: Back of the envelope oceanic CO2 calculations
- Sender:
- Followup-To: sci.geo.fluids
- Organization: Code 916, NASA Goddard Space Flight Center
-
- Hello everyone. Today in Chem class we discussed Henry's Law which relates
- the vapour pressure of a gas to the amount that would dissolve in a fluid
- solvent for a specific concentration and temperature. For kicks and giggles,
- I came back and tried to calculate the amount of CO2 in the oceans, given
- that the density was 1 kg/m3 (yep, just pure water) and the volume of the
- ocean was 1.35 x 10^15 m3 (Biogeochemistry, Schlesinger, 1992). I assumed a
- CO2 concentration of 380 ppm, for a partial pressure of 0.288 Torr at a
- standard temperature of 298 K and pressure 1 atm. For CO2, the Henry's LAw
- constant was 1.25 x 10^6 Torr in pure water (no data on seawater since it
- is variable due to saline content), and Henry's Law goes like this:
-
- partial pressure (CO2)= Henry's Const. x mole fraction (CO2)
-
- Furthermore, the mole fraction was defined as : # moles CO2/ (# moles CO2
- + # moles H2O)
-
- Working it all out, the answer I came up with was 1.52 x 10^5 metric tons.
- Now recalling that the flux of CO2 into and out of the oceans is a bit
- larger than that... I'm curious as to whether this calculation is way off
- as a result of the lack of variance in temperature and salinity, or if it
- is at least in the neighborhood.
-
- Anyone have any evidence of total oceanic CO2 content?
-
- ***This is not meant as a legitimate estimate, so don't flame me for this!***
- (I'm just curious as to how good or bad this approximation is... I
- have a big feeling that it stinks, but want to make sure.)
-
- Bryan Hannegan
- hannegan@halo.ps.uci.edu
- Dept. of Geosciences, University of CA, Irvine
-
-