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- Xref: sparky sci.astro:9409 sci.optics:926
- Path: sparky!uunet!dove!gilligan
- From: gilligan@bldrdoc.gov (Jonathan M. Gilligan)
- Newsgroups: sci.astro,sci.optics
- Subject: Re: cleaning mirrors - NOT!
- Message-ID: <5337@dove.nist.gov>
- Date: 2 Sep 92 21:59:00 GMT
- References: <1992Sep2.141132.9895@cs.ucf.edu>
- Sender: news@dove.nist.gov
- Followup-To: sci.astro
- Organization: National Institute of Standards and Technology
- Lines: 29
-
- In article <1992Sep2.141132.9895@cs.ucf.edu> clarke@acme.ucf.edu (Thomas Clarke) writes:
- >So I got some pool chlorine (stronger than chlorox) and put a
- >little on the mirror. To my horror, the aluminum film
- >began to dissolve. Quickly rinsing it under water I partly
- >saved the coating; I suspect what remains is about 50% reflective
- >now.
- >
- >At least I know how to remove the old coating before I send
- >it out for recoating :-)
- >
- >Anyone know what the chemistry of an Al film plus
- >sodium hypochlorite solution would be?
-
- I don't know the exact chemistry, but in my experience using XeCl
- excimer lasers and aluminum ultraviolet mirrors, I've found that even
- a very small concentration of chlorine or HCl in the air can quickly
- fog a mirror. Bulk aluminum exposed to HCl and water forms a green
- salt. The CRC lists HCl as a solvent for elemental aluminum. Aluminum
- oxide (Al_2 O_3) is listed as very slightly soluble in acids and
- alkalis, while the oxide trihydrates are listed as soluble. These
- properties are also known to people who keep house, as chlorine bleach
- (Ajax, Comet, etc.) will pit the surface of aluminum pans.
-
- ---Jon
-
-
- --
-
- Disclaimer --- The government probably disagrees with my opinions.
-