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- From: ag3l+@andrew.cmu.edu (Arun K. Gupta)
- Newsgroups: sci.physics
- Subject: Re: Volume occupation
- Message-ID: <keXkdGi00aw=8OgEVs@andrew.cmu.edu>
- Date: 16 Aug 92 18:09:22 GMT
- Article-I.D.: andrew.keXkdGi00aw=8OgEVs
- Organization: Physics, Carnegie Mellon, Pittsburgh, PA
- Lines: 48
-
-
- >From: sichase@csa2.lbl.gov (SCOTT I CHASE)
- >Subject: Re: Volume occupation (was Re: Vector Bosons?)
- >Date: 16 Aug 92 19:40:55 GMT
- >
- >In article <1992Aug16.013415.3630@cerberus.ulaval.ca>, yergeau@cornu.phy.ulaval.ca (Francois Yergeau) writes...
- >>
- >>I countered that plain electrostatic interaction must come before that,
- >>making the following argument: forget about spin, and solve the good
- >>old Schrodinger equation for a hydrogen atom. You get a nice
- >>non-collapsing ground state that occupies some space. Add more
- >>electrons and protons, resolve and lo, the occupied volume grows.
- >>
- >>Anyone cares to comment?
- >
- >Sure. I agree 100%. Even without the exclusion principle, EM repulsion
- >would keep your chair leg from passing through the floor - but chemistry
- >would be so different that trees would not likely exist from which to
- >make the table.
-
- [deleted]
-
- >-Scott
- >--------------------
-
- Consider a hydrogen molecule. The two electrons can be in a spin-antisymmetric,
- space-symmetric or a spin-symmetric, space-anti-symmetric state (the exclusion
- principle). Since spin interaction energies are very small, to a first approx-
- imation computation of the ground state is a boson-vs.-fermion comparison.
-
- It turns out that the space-symmetric state has lower energy. Even though the
- electrons tend to occupy the same region of space, the positive energy of
- repulsion between electrons and protons is overbalanced by the negative
- energy of attraction of the protons towards the overlap region. In fact, for
- a space- anti-symmetric wave function, the hydrogen atoms do not bond.
-
- It is not at all clear to me that in a bosonic-electron system, the electrons
- will not all occupy one state, not very much larger than a few atomic orbitals
- in spatial extent, with the nuclei all very close to this very dense negatively
- charged cloud. That is bosonic electrons would very effectively screen the
- nuclear charge and this matter would be very much more dense than normal
- matter. Nor is it obvious that the volume of matter will be prop-
- oitional to the number of atoms.
-
- Anyone to whom the answer is obvious, please explain.
- thanks in advance.
- -arun gupta
- ag3L@andrew.cmu.edu
-