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- Newsgroups: sci.physics.fusion
- Path: sparky!uunet!gatech!rpi!usc!wupost!spool.mu.edu!agate!rsoft!mindlink!a752
- From: Bruce_Dunn@mindlink.bc.ca (Bruce Dunn)
- Subject: Re: The Dunn Summary
- Organization: MIND LINK! - British Columbia, Canada
- Date: Tue, 5 Jan 1993 17:01:14 GMT
- Message-ID: <19256@mindlink.bc.ca>
- Sender: news@deep.rsoft.bc.ca (Usenet)
- Lines: 77
-
- Tom Droege writes:
-
- >
- > The big mystery is how P&F run. To my knowledge they have never told us.
- > The early paper said "sealed with parafilm". What the heck is parafilm?
- > But if they seal the cells, they have to vent the gas. My guess it that
- > they are Type 2, but perhaps someone can fill in. Remember that even
- > Hawkins was never in the back room, so we have to get the answer from P or
- > F.
-
-
- Parafilm (tradename) is a sheet of stretchy, slightly sticky, wax.
- Imagine if you can a cross between Saran wrap, paraffin wax, sheet rubber and
- the skin of a bubble-gum bubble. It comes on a roll, interleaved with paper
- to keep it from sticking to itself (which it will do under moderate finger
- pressure). It is possible to make an air tight seal with it on a beaker, but
- the seal won't withstand any great pressure differential (if pressure builds
- up in a Parafilm sealed container, the Parafilm bulges out, followed a little
- later by a "Pffft" as a hole develops).
-
- I presume that the P&F cell is sealed with Parafilm, with a small hole
- somewhere in the system for venting. This would then qualify as a "Type 2,
- no recombiner, bubbler or orifice" cell.
-
- The point of why I lumped together no-recombiner cells with bubblers and
- orifices is that with the continued flow of gas caused by the electrolysis, a
- small orifice is probably just as good as a bubbler in keeping air (and
- nitrogen) from getting at the cell. Bubblers and orifices hower do not seem
- to me to be equivalent when a recombiner is used. In this case, once
- charging is finished, there is no continuous flow of gas and nitrogen could
- come back in through an orifice, but not through a bubbler.
-
-
- > The only first class experiment that I know of (McKubre) runs with a 100%
- > D2 fill. I guess 10,000 psi is a lot of kPa. McKubre says that this high
- > pressure completly prevents the formation of O2 bubbles. Perhaps someone
- > can explain this. Where does the O go if it does not make bubbles? But he
- > has also claimed excess heat at the much lower 50 psi.
-
- 10,000 psi would be about 70 MPa, or 70,000 kPa (1 atmosphere is roughly 100
- kPa). Any bubbles attempting to form would be very small, squashed by the
- pressure. Perhaps oxygen simply dissolves in the electrolyte as it is
- formed, as a result of the pressure.
-
-
-
- > How about it Bruce, do you want to be keeper of the matrix? If so I will
- > start sending everything I can find. At present I am keeping what I know
- > in my head and trying to do the same job as you in trying to find a common
- > thread in the successful experiments.
-
- Sorry - but no thanks. I am not well enough up on what everone is doing to
- be able to adequately do this. I am not an experimenter in this field. I do
- however have some practical experience in dissolved gases - I do high
- pressure liquid chromatography and have to use helium sparging each morning
- to flush the nitrogen and ocygen out of my solvents.
-
- I see from your posting that there should be a "Type 6, closed and
- pressurized". I also see that "Type 5, recombiner, syringe or bellows" has
- been run with a fill of inert gases - maybe a separate classification is
- needed. Hoyt Sterns mentions yet another type of cell, with a recombiner but
- evacuated after the initial generation of oxygen during charging.
-
- The point of my rather speculative posting was not to make an exhaustive
- classification of cells, but to point out that little attention seems to have
- been given to gas compositions in cells (in comparison for example with the
- concentration on the surface finish, impurities etc. of cathodes). I am
- particularly struck by the fact that the most positive results seem to have
- come from the more "open" cells where dissolved nitrogen levels would be
- expected to be higher.
-
-
-
-
-
- --
- Bruce Dunn Vancouver, Canada Bruce_Dunn@mindlink.bc.ca
-