home *** CD-ROM | disk | FTP | other *** search
- subject = Chemistry
- title = Lead
- papers = Lead is a lustrous, silvery
- metal that tarnishes in the presence of air and becomes a dull bluish
- gray. Soft and flexible, it has a low melting point (327 ░C). Its chemical
- symbol, Pb, is from plumbum, the Latin word for waterworks, because of
- lead's extensive use in ancient water pipes. Itsatomic number is 82; its
- atomic weight is 207.19.
-
- Lead and lead compounds can be highly toxic
- when eaten or inhaled. Although lead is absorbed very slowly into the
- body, its rate of excretion is even slower. Thus, with constant exposure,
- lead accumulates gradually in the body. It is absorbed by the red blood
- cells and circulated through the body where it becomes concentrated in
- the soft tissues, especially the liver and kidneys. Lead can cause damage
- in the central nervous system and apparently can damage the cells making
- up the blood-brain barrier that protects the brain from many harmful chemicals.
-
- Symptoms
- of lead poisoning include loss of appetite, weakness, anemia, vomiting,
- and convulsions, sometimes leading to permanent brain damage or death.
- Children who ingest chips of old, lead-containing paint or are exposed
- to dust from the deterioration of such paint may exhibit symptoms. Levels
- of environmental lead considered nontoxic may also be involved in increased
- hypertension in a significant number of persons, according to studies
- released in the mid-1980s. As a result, the U.S. Centers for Disease Control
- in recent years have been revising downward the levels of environmental
- lead that it would consider safe. At one time, lead poisoning was common
- among those who worked with lead, but such workplace hazards have been
- largely curtailed.
-
- Lead has been used by humans since ancient times.
- It was used in ancient Egypt in coins, weights,
- ornaments, utensils,
- ceramic glazes, and solder. Lead is mentioned in the Old Testament. The
- Romans
- conveyed drinking water in lead pipes, some of which are still in operation.
- Roman slaves
- extracted and prepared the lead, describes a disease among
- the slaves that was clearly lead poisoning. Because of their potential
- toxicity, lead water pipes are no longer being installed. The greatest
- single use of lead metal today is in the plates of storage batteries for
- automobiles.
-
- The protective oxidation layer formed by lead in contact
- with such substances as air, sulfuric acid,
- and fluorine makes it highly
- resistant to corrosion. For this reason, lead has been used to make
- drainage
- pipes and lead chambers in sulfuric acid factories. It is also used as
- a roofing material. The
- softness and malleability of lead make it useful
- for sheathing telephone and television cables. Lead is
- used in solder
- because of its low melting point. When combined with tin, lead forms solder
- alloys
- that are stronger than lead alone, with melting points lower than
- those of either original metal.
-
- Lead has the highest density of all
- metals in common use, which, for example, makes it useful as a
- counterweight
- in the keels of ships. Because of their high density, lead bullets and
- shot encounter
- little air resistance and thus achieve excellent striking
- power. Shot is produced by allowing molten
- lead to drip down from heights
- up to 38.10 m (125 ft). The drops become spherical and are
- condensed
- by the cooling action of the air before being collected in a tank filled
- with water or oil.
- Lead's density and softness also make it highly suitable
- for damping sound and vibrations. To isolate
- them from vibration, heavy
- machinery and even whole buildings are placed on lead blocks. Because
- the
- effectiveness of shielding against gamma and X rays depends largely on
- the density of the shield,
- lead is used in the protective shielding of
- X-ray machines and nuclear reactors.
-
-
- Tetraethyl lead or tetramethyl
- lead (PbEt4) has often been added to gasoline to improve engine efficiency
- and
- reduce gasoline consumption in automobiles. Because of the toxic effect
- of lead on the
- environment, however, plans call for phasing out this
- use. Lead azide is sensitive
- to striking and is highly explosive; it
- is frequently used as a detonator of explosives. Lead iodide is a
- light
- yellow substance that is used as a dye in such processes as coloring bronze.
- It has
- light-sensitive properties comparable to those of silver salts.
-
-
- More
- Uses
-
- ╖ the metal and the dioxide are used in storage batteries, cable
- covering, plumbing, ammunition
- ╖ manufacture of PbEt4 - an antiknock
- compound in petrol.
- ╖ environmental concern with lead poisoning, (and
- cheaper unleaded petrol prices) is slowly resulting in less use of lead
- in petrol
- ╖ the metal is very effective as a sound absorber, a radiation
- shield around X-ray equipment and nuclear reactors
- ╖ used extensively
- in paints, although recently the use of lead in paints has been drastically
- curtailed to eliminate or reduce health hazards
- ╖ the oxide is used
- in producing fine "crystal glass" and "flint glass" with a high refractive
- index for achromatic lenses
- ╖ solder
- ╖ used by the Romans for plumbing
- (the decline of the Roman empire is attributed to lead in the water supply!)
-
- ╖ used to contain corrosive liquids
- ╖ alloying
- ╖ cable covering
-
- ╖ ammunition
- ╖ shield against X-rays
- ╖ oxide used to produce crystal
- glass
- ╖ insecticides
-
-
-
-