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- From: Bruce Hamilton <B.Hamilton@irl.cri.nz>
- Newsgroups: sci.chem,sci.answers,news.answers
- Subject: Sci.chem FAQ - Part 3 of 7
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- Date: Thu, 15 Jan 2004 22:10:05 +1300
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- Last-modified: 22 October 1999
- Version: 1.17
-
- Subject: 11. Traditional Specialist Chemical Information Sources
-
- 11.1 Where can I find spectral libraries/databases?
-
- The most likely place is near to an instrument. These are not usually
- in general technical libraries, but are kept near the instruments.
- A polite request to the person in charge of the instrument should identify
- who to contact for permission to use the library or database. There is
- some spectral information in reference texts, such as the Rubber Handbook
- and the Merck Index, but most compilations are now so large that they cover
- several volumes. There are several compilations that are available
- commercially, either in hard copy (HC) or CD-ROM (CD) - which is usually
- more expensive because of the included searching software. Chemical
- manufacturers, such as Aldrich, may also sell spectral libraries, eg
- IR $495(HC) [1], FT-IR $875(HC) or $1578(CD) [2], 60MHz H1 NMR $495(HC) [3],
- and 300MHz H1 + 75MHz C13 NMR $1072(HC) [4], as well as offering
- compilations from government agencies, eg the NIST/EPA/NIH Mass Spectral
- database $1320(CD)[5]. The databases are also sold by several instrument
- manufacturers. One commercial supplier of spectral information ( Fiveash
- Data Management, Inc. ) may be accessible via the Internet [6].
-
- 11.2 Where can I find polymer chemistry information?
-
- The first stop should be the multi-volume Encyclopedia of Polymer Science
- and Engineering [7], which should be in most technical libraries. Specific
- polymers are covered in much less detail in Kirk Othmer. There are
- several journals devoted to polymer science and chemistry, including the
- Journal of Polymer Science.
-
- 11.3 Where can I find analytical chemistry information?
-
- There is a sci.chem.analytical group where specific questions can be
- posted after you have attempted to find the information in the following
- sources. For qualitative information, the spot test books by Fiegl [8,9]
- and "Semi-micro Vogel"[10], are good starting points. For introductory
- quantitative analysis, "Quantitative Inorganic" [11],"Practical Organic
- Chemistry"[12] by Vogel are good introductions to non-instrumental
- techniques. The multi-volume "Treatise on Analytical Chemistry" by
- Kolthoff and Elving [13] comprehensively discusses most techniques, and
- several volumes of the ACS Series "Techniques in Chemistry" [14] also cover
- analytical procedures. " Instrumental Methods of Analysis" by Willard,
- Merritt, Dean and Settle [15], and "Analytical Instrumentation Handbook" by
- Ewing [16] provide a good introduction to chemical instrumentation. Most
- educational institutions will have equivalent texts if they are not using the
- above.
-
- For specific analyses it is often desirable to use standard procedures,
- especially if your laboratory is seeking ISO 9001 accreditation, or if the
- results are likely to be disputed. Some well known compilations of standard
- methods include:-
-
- Laboratory Reagents
- - usually specified by manufacturers or chemical societies
- BDH 'Analar' Standards for Laboratory Chemicals [17]
- ACS Reagent Chemicals [18]
-
- Materials, Industrial Chemicals, and Finished Products.
- - usually the monographs in the following volumes also specify assay and
- impurity limits, as well as detailing the analytical procedure.
- ASTM - Issued annually, cover physical and chemical testing of a wide range
- of industrial products. Often require specialised test equipment.
- ISO - International standards, usually derived from US(ASTM), UK(BSI) or
- FRG(DIN) standards. Similar to above.
-
- Pharmaceuticals
- - usually the pharmacopoeia have monographs and methods, but some methods
- are also specified in National Formulary or Pharmaceutical Codex volumes,
- which may be separate from the pharmacopoeia.
- - common pharmacopoeia are USP, BP, and EP - with Martindale [19] often used
- to ascertain where and when a specific monograph appeared.
-
- Food
- - often the procedures specified in Government legislation.
- - The Official Methods of the AOAC [20] covers many routine US methods.
-
- Environmental Pollution
- - the procedures are usually specified in the relevant legislation, and
- frequently US EPA procedures are used. Several common EPA procedures are
- now available on computer disk [21,22].
-
- Petroleum
- - usually covered by ASTM, ISO or DIN, but there are some unique IP
- ( Institute of Petroleum - UK ) procedures that are also used.
- - "Chromatography in Petroleum Analysis"[23], summarises popular techniques.
-
- Gases
- - instrument manufacturers have fairly detailed procedures for process gases.
- - "The Analysis of Gases by Chromatography"[24], provides useful examples.
-
- Water and Wastewater
- - the APHA/WWA/WPCF standard methods are most often used [25]
- - many tests are also covered by ASTM, ISO, and DIN procedures
- - alternative techniques are described in "Water Analysis" [26]
- - organics in water are covered by Crompton [27]
- - most aspects of water chemistry are detailed in Franks [28]
-
- Sample Preparation
- - consumable and instrument manufacturers often provide detailed manuals
- and guides free.
- - "Methods of Decomposition in Inorganic Analysis" [29] covers a wide range
- of preparations for spectroscopy.
- - The "Handbook of Analytical Derivatization Reactions" [30] and the
- " Handbook of Derivatives for Chromatography" [31] cover many of the
- techniques for gas and liquid chromatography.
-
- Obviously there are several journals devoted to various aspects of
- analytical chemistry. The April issue of Analytical Chemistry publishes
- a review of papers published during the previous two years. The review
- alternates between Fundamental and Application Reviews and is a quick means
- of catching current trends if you are unable to locate an expert.
-
- 11.4 Where can I find environmental chemistry information?
-
- There are several standard texts used by environmental chemistry classes
- that provide good general introductions, eg "Environmental Chemistry" [32]
- "Fundamentals of Environmental Chemistry [33], and "Environmental Organic
- Chemistry" [34]. They should be available in most technical libraries. The
- monthly journal "Environmental Science and Technology" covers most aspects
- of environment chemistry. "Chemosphere" concentrates on toxins such as PCBs
- and Dioxin, and " Science of the Total Environment also covers many aspects.
- Government agencies such as the EPA also publish large amounts of
- information, and many environmental groups also provide significant amounts
- of technical information. There are a range of specialist texts that cover
- specific pollutants, eg "Metals and their Compounds in the Environment:
- Occurrence, Analysis and Biological Relevance" [35].
-
- The sci.environment Usenet group may well be a better place to request
- environmental chemistry information than sci.chem, but please remember
- to move discussions to talk.environment.
-
- 11.5 Where can I find physical chemistry information?
-
- General introductory information will be available in any technical library
- where chemistry is taught, and one of the more popular modern texts is
- "Physical Chemistry" by P.W.Atkins [36], and a classical text is
- "Textbook of Physical Chemistry" by S.Glasstone [37]. The multi-volume ACS
- series "Physical Methods of Chemistry"[38] also covers many physical
- chemistry techniques. There are also the Journal of Chemical Physics and the
- Journal of Physical Chemistry. Frankly, I would not have a clue where else
- to go.
-
- 11.6 Where can I find inorganic chemistry information?
-
- General introductory information will be available in any technical library
- where chemistry is taught. One popular text is "Inorganic Chemistry" by
- D.F.Shriver, P.W.Atkins, and C.H.Langford [39], which also has the answers
- available as a separate book. "Inorganic Vogel"[40], also discusses the theory
- of the analyses. There are three major multi-volume inorganic encyclopedias.
- Mellor is frequently found in public libraries, and provides a broad cover
- of the field, however the more comprehensive is Gmelin [41], which will be
- available in most institution libraries. The more recent developments and
- mechanisms are covered in the multi-volume "Encyclopedia of Inorganic
- Chemistry" [42], which may be difficult to find due to its $2500 price.
- "Advanced Inorganic Chemistry" [43] by F.A.Cotton and G.Wilkinson provides a
- good base to start. There are several journals that cover aspects of
- inorganic chemistry.
-
- 11.7 Where can I find organic chemistry information?
-
- General introductory information will be available in any technical library
- where chemistry is taught. One popular modern text is " Organic Chemistry "
- by T.W.G.Solomons [44], but my favourite is "Organic Chemistry"[45] by Fieser
- and Fieser - a much more practical discussion of organic molecules.
- Once you are familiar with organic chemistry mechanisms then "Advanced
- Organic Chemistry" by Carey and Sandberg [46] is a good overview.
-
- There are several compilations of organic synthesis techniques to assist
- researchers. The multi-volume sets "Organic Reactions" [47], and "Reagents
- for Organic Synthesis" [48], are examples of sets that will be available from
- institution libraries. There are some good theoretical texts available, eg
- "The Logic of Chemical Synthesis" [49]. For specific preparation and
- properties of individual compounds, then Heilbron [50] and Beilstein [51],
- are the initial resources of choice. There are several journals devoted to
- organic chemistry in general, including Journal of Organic Chemistry,
- Tetrahedron, etc.. Specific branches of organic chemistry, such as
- Carbohydrates, Lipids, or Proteins have their own journals, as do
- applications such as pharmaceuticals and pesticides.
-
- 11.8 Where can I find industrial chemistry information?
-
- The best single volume remains Shreve's "Chemical Process Industries" [52].
- There are three major multi-volume encyclopedias, Kirk Othmer, Ullmann,
- and McKetta, that cover many aspects of industrial chemistry and at
- least one is usually available in a public library. There are also several
- journals that provide good overviews of industrial chemistry, the easiest
- to read being C&EN, and Chemtech. Research is usually published
- in Industrial and Engineering Chemistry ( which is an excellent source
- for historical research ), and specialist chemical engineering journals.
-
- 11.9 Where can I find pharmaceutical chemistry information?
-
- Pharmaceutical research often is initially reported in patent literature,
- consequently patent searching is a good place to start. The Merck Index is
- focused on pharmaceuticals, and also provides excellent leads to the
- research literature. There are several pharmaceutical chemistry books, such
- as Goodman and Gilman [53], and "Essentials of Medicinal Chemistry" [54],
- that provide overviews of the field. The Journal of Pharmaceutical Chemistry
- is a good source for research articles. Details of chemicals appearing in
- formulated products can be found in the "Handbook of Pharmaceutical
- Excipients" [55].
-
- ------------------------------
-
- Subject: 12. Nomenclature
-
- 12.1 What are CAS Registry Numbers?
-
- When chemicals are first encountered by the Chemical Abstracts Service, they
- are assigned a unique number when they are registered. These numbers are not
- related to any structure or property of the molecule, they are arbitrarily
- assigned. It should be remembered that occasionally a compound may be
- accidentally assigned two or more numbers - especially industrial products
- that have not been completely characterised. When this is discovered, one of
- the numbers is no longer used. The numbers usually take the form of
- [xx-yy-z to xxxxxx-yy-z] and square brackets are often used in monographs to
- identify the CAS Registry Number [RN]. The easiest way to locate the CAS RN
- for commercially-available chemicals is to look in suppliers catalogues
- ( eg Aldrich) or compilations ( eg Merck or Hawley ), almost all chemical
- texts now list the RN, and several ( eg Merck Index and Aldrich ) have a
- cross-reference Index. The RN is extremely useful for on-line searching of
- Chemical Abstracts and several other popular chemistry-related databases,
- but is not particularly useful for the hardcopy version, except to confirm
- compound identity.
-
- 12.2 What are the correct names of recently-discovered elements?
-
- The Transfermium Working Group was established in 1986 by the International
- Union of Pure and Applied Chemistry (IUPAC) and the International Union of
- Pure and Applied Physics (IUPAP). The working group published several
- reports, and then recommended that elements should not be named after living
- persons [1]. This greatly upset the USA - who wanted to name an element after
- G. Seaborg. After protracted negotiations, a compromise selection of names
- was finally approved by the IUPAC Commission on Nomenclature in Inorganic
- Chemistry, the IUPAC Inorganic Division, the IUPAC Bureau, and the selection
- was eventually ratified by the IUPAC Council meeting in Geneva during August
- 1997 [2].
-
- 101 Mendelevium Md D. Mendeleev (Russia)
- 102 Nobelium No Nobel Institute (Sweden)
- 103 Lawrencium Lr E. Lawrence (USA)
- 104 Rutherfordium Rf E. Rutherford (NZ)
- 105 Dubnium Db Dubna = Russian Research Centre
- 106 Seaborgium Sg G. Seaborg (USA)
- 107 Bohrium Bh N. Bohr (Denmark)
- 108 Hassium Hs Latin name for German state of Hesse
- 109 Meitnerium Mt L. Meitner (Austria)
-
- Note that Hesse is where the German heavy-element laboratory is based.
- The Gesellschaft fur Schwerionenforschung (GSI) was responsible for the
- first man-made creation of elements 107-110. The compromise will now move
- attention to the naming the recently-discovered elements 110-112.
-
- 12.3 What is the nomenclature system for CFCs/HCFCs/HFCs?
-
- The CFC naming system was developed by T.Midgley,Jr. and A.L.Henne in 1929,
- and further refined by J.D.Park. Originally, organic molecules that contained
- Chlorine and Fluorine were all referred to as CFCs. Today, the group is
- subdivided into CFCs, HCFCs, and HFCs. The naming system consists of:-
-
- CFC-01234a where 0 = number of double bonds ( omitted if zero )
- 1 = Carbon atoms - 1 ( omitted if 0 )
- 2 = Hydrogen atoms + 1
- 3 = Fluorine atoms
- 4 = Chlorine atoms replaced by Bromine ("B" prefix added )
- a = letter added to identify isomers, the "normal" isomer
- in any number has the smallest mass difference on each
- carbon, and a, b, or c are added as the masses diverge
- from normal.
-
- If the compound is cyclic, then the number is prefixed with "C". There are
- several other refrigerants, some of which are hydrocarbons, hydrocarbon
- blends, or CFC blends. Full details of the nomenclature system are specified
- in ANSI/ASHRAE Standard 34-1992 with additional annual supplements. Chemical
- names are frequently used in place of the numbers for common materials
- - such as trichloroethylene and chloroform. The specified ANSI/ASHRAE
- prefixes were FC ( FluoroCarbon ), or R ( Refrigerant ), but today most are
- prefixed by more specific classifications - such as CFC, HCFC, and HFC.
-
- CFC-11 CCl3F trichlorofluoromethane [75-69-4]
- CFC-12 CCl2F2 dichlorodifluoromethane [75-71-8]
- CFC-113 CCl2F-CClF2 1,1,2-trichlorotrifluoroethane [76-13-1]
- HCFC-22 CHClF2 chlorodifluoromethane [75-45-6]
- HCFC-123 CHCl2-CF3 2,2-dichloro-1,1,1-trifluoroethane [306-83-2]
- HCFC-123a CHClF-CClF2 1,2-dichloro-1,1,2-trifluoroethane [354-23-4]
- HFC-23 CHF3 trifluoromethane [75-46-7]
- HFC-134 CHF2-CHF2 1,1,2,2-tetrafluoroethane [359-35-3]
- HFC-134a CH2F-CF3 1,2,2,2-tetrafluoroethane [811-97-2]
- R-20 CHCl3 chloroform [67-66-3]
- R-22B1 CHBrF2 bromodifluoromethane [1511-62-2]
- R-1120 CHCl=CCl2 trichloroethylene [79-01-6]
- R-1150 CH2=CH2 ethylene [74-85-1]
- R-C316 C4Cl2F6 1,2-dichlorohexafluorocyclobutane
-
- Another technique for naming CFCs uses the addition of 90 to the CFC number
- to produce a "def" number which corresponds to the CHF composition. If
- (e + f) < (2d + 2), then additional atoms are required for saturation. This
- technique has been described in detail in the Journal of Chemical Education
- [3].
-
- ASHRAE +90 Empirical Composition Formula
- C H F (+Cl)
- CFC-11 101 1 - 1 3 CCl3F
- CFC-12 102 1 - 2 2 CCl2F2
- HCFC-22 112 1 1 2 1 CHClF2
- HCFC-123 213 2 1 3 2 CHCl2-CF3
- HFC-134a 224 2 2 4 - CH2F-CF3
-
- Halons are numbered according to a totally different system developed by
- the US Army Corps of Engineers, and the prefix term is always "Halon".
- Hydrogen is not numbered, and terminal zeros are not expressed.
-
- Halon-0123 where 0 = number of carbon atoms
- 1 = number of fluorine atoms
- 2 = number of chlorine atoms
- 3 = number of bromine atoms
-
- Halon-1211 CBrClF2 bromochlorodifluoromethane [353-59-3]
- Halon-1301 CBrF3 bromotrifluoromethane [75-63-8]
- Halon-2402 CBrF2-CBrF2 1,2-dibromo-1,1,2,2-tetrafluoroethane [124-73-2]
-
- 12.4 How can I get the IUPAC chemical name from traditional names?
-
- It depends. Usually the quickest way is to look the name up in a chemical
- supplier's catalog, MSDS, or a standard text like Merck or Hawley. You can
- also often find the correct name if you refer to an old chemistry text that
- lists both the traditional and IUPAC naming conventions. Some traditional
- or common names also refer to mixtures of chemicals, eg aqua regia, piranha
- solution.
-
- One reason why traditional names have been replaced is because the same name
- could be used for different compounds. An example is the use of caprylic to
- describe 1-Octanol and 2-Octanol, and attempts to qualify the name with
- "primary" and "secondary" were less than successful. Octyl alcohol has been
- used to describe both 1-octanol and 2-ethylhexanol, thus explaining why the
- well known dioctyl phthalate (DOP) is actually bis(2-ethylhexyl) phthalate.
- The following examples highlight the diversity of names often encountered.
-
- Carbon Alkane Alcohol Aldehyde Acid
-
- 1 methane methanol form- formic
- carbinol
- 2 ethane ethyl acet- acetic
- methyl carbinol
- 3 n-propane n-propyl propion- propionic
- ethyl carbinol
- 4 n-butane n-butyl n-butyr- n-butyric
- propyl carbinol
- 5 n-pentane n-amyl n-valer- n-valeric
- butyl carbinol
- 6 n-hexane hexyl capro- caproic
- amyl carbinol caproic
- 7 n-heptane enanthyl enanth- enanthic
- enanthic
- hexyl carbinol
- 8a n-octane capryl capryl- caprylic
- primary caprylic caprylic
- heptyl carbinol
- 1-octanol
- 8b capryl
- secondary caprylic
- methyl hexyl carbinol
- 2-octanol
- 9 n-nonane pelargonic pelargonic pelargonic
- octyl carbinol
- 10 n-decane capric capr- capric
- nonyl carbinol capric
- 12 n-dodecane lauryl laur- lauric
- lauric lauryl
- 14 n-tetradecane myristyl myrist- myristic
- 16 n-hexadecane cetyl palmit- palmitic
- cetane
- 18 n-octadecane stearyl stearic
- 20 n-eicosane arachidyl arachidic
-
- Primary
- - alcohol R1CH2OH
- - amine R1NH2
- eg normal straight chain normal octane n-octane
- normal butanol 1-butanol
- iso branched chain iso-butane 2-methylpropane
- iso-butanol 2-methyl-1-propanol
- iso-octane 2,2,4-trimethylpentane
-
- Secondary
- - alcohol R1R2CHOH
- - amine R1R2NH
- eg sec-butanol 2-butanol
- iso-propanol 2-propanol
-
- Tertiary
- - alcohol R1R2R3COH
- - amine R1R2R3N
- eg tert-butanol 2-methyl-2-propanol
-
- - substitution onto the benzene ring
- 1,2 = ortho ortho-xylene
- 1,3 = meta meta-xylene
- 1,4 = para para-xylene
-
- However other names get more tricky, especially historical names, where
- several names may be used for the same chemical and, even worse, different
- chemicals can be described by the same name. Examples include:-
- - calcium carbonate = limestone, chalk, calcite.
- - calcium hydroxide = slaked lime, hydrated lime, caustic lime.
- - calcium oxide = calx, lime, quicklime, unslaked lime, burnt lime.
- - hydrochloric acid = muriatic acid, spirits of salts.
- - nitric acid = aqua fortis.
- - potassium carbonate = potash, artificial alkali, vegetable alkali.
- - potassium hydroxide = caustic potash, lye.
- - sodium carbonate - any form = soda, natural alkali, mineral alkali.
- - anhydrous = soda ash.
- - dodecahydrate = sal soda, washing soda.
- - monohydrate = soda crystals.
- - sodium chloride = rock salt.
- - sodium hydroxide = caustic soda, lye, soda lye.
- - sulfuric acid = oil of vitriol
-
- Some old chemical terms are seldom encountered these days, but have very
- specific meanings, eg
- " flowers " described any product of sublimation, hence "flowers of sulfur".
- " specific " in front of any quantity means " divided by mass ", hence
- "specific gravity".
- " ether " described a volatile liquid, not only compounds with the Cx-O--Cy
- structure, and also often known today as "spirit".
- " aromatic " described a liquid that had an aroma, not only those derived
- from benzene, or which benzene ring structure.
- " oil " described a liquid that was not miscible with water, thus it
- described different products in different chemical industries :-
- - Essential oils = volatile and odoriferous liquid plant extracts.
- Essential oils can be obtained by extraction or distillation ( steam ),
- often contain terpenes ( based on the isoprene structure ), are usually
- smelly ( aromatic ), and are used for perfumes, flavours and aromas, eg
- lemon oil and pine oil.
- - Triglyceride oils = fats and oils based on the glycerol molecule that
- can be obtained from plant and animal material, frequently by melting or
- cold pressing. They are a significant, and important, component in our
- diet, eg soya oil, lard, fish oils, and anhydrous milk fat.
- - Petroleum oil = a mixture of a large number of hydrocarbons that are
- usually derived from 0.1 to 3 billion-year-old organic matter. Crude oil
- can contain hundreds of hydrocarbons with one to sixty carbon atoms, and
- the hydrocarbons are usually grouped and reported by type, eg alkane
- ( paraffin ), alkene ( olefin ), or arene ( aromatic ).
-
- Almost all old industries had easy-to-remember names for chemicals they
- commonly encountered, but today many of those names can cause confusion
- if used outside the industry. Some common examples, just from the petroleum
- industry alone are:-
- - " ether " is a volatile hydrocarbon fraction that does not contain the
- Cx-O-Cy structure, eg petroleum ether ( aka petroleum spirit ).
- - " naphthene " is a cyclic paraffin, does not contain naphthalene, and is
- not a major component of naphtha ( refer Section 27.5 ).
- - Benzene, toluene and xylene are often called benzol, toluol, and xylol,
- even though they do not contain an -OH group.
- - Benzine ( ligroin ) was a saturated hydrocarbon fraction that boiled
- between 20C and 135C. Gasoline/petrol fractions are still called benzine
- by some older people.
- - Diesel fuel is often called "gas oil", which is a historical term for
- hydrocarbon distillate fractions. Atmospheric gas oil has a boiling
- range between 220C - 450C, and vacuum gas oil boils from 350C to 550C.
-
- 12.5 What does "omega-3 fatty acids" mean?
-
- Chemists recognise that they should always number carbon chains from the
- end with the functional group, so the location of double bonds in
- unsaturated fatty acids are numbered from the carboxylic acid end, and
- are usually designated by "delta" in their abbreviated names.
-
- Biochemists are more interested in the actual role that chemicals play,
- consequently they will consider the position from the end that is important.
- In the case of natural fatty acids the double bonds are usually cis
- configured, and it is the distance of the first double bond from the
- terminal end of the carbon chain that is important. They use "omega" to
- signify that the double bond is cis, and they are counting from the other
- end. The great advantage is that chain length can be ignored, and compounds
- that are subjected to the same biochemical processes are grouped together.
-
- In 1967, the IUPAC/IUB commission responsible for lipid nomenclature
- recommended that for unsaturated fatty acids with cis double bonds, that
- the "omega" symbol be replaced with "n-x", where n = the length of the
- carbon chain, and x is the distance from the terminal end.
-
- Some examples:-
-
- Common Chemical Chemical Biochemical
- Name Name d = delta o = omega
-
- Oleic cis-9-octadecenoic c-C18:1d9 C18:1o9
- Elaidic trans-9-octadecenoic t-C18:1d9 -
- Ricinoleic D-(+)-12-hydroxy-octadec-cis-9-enoic c-C18:1d9-12OH -
- Linoleic cis-9,12-octadecadienoic c-C18:2d9 C18:2o6
- alpha Linolenic cis-9,12,15-octadecatrienoic c-C18:3d9 C18:3o3
- gamma Linolenic cis-6,9,12-octadecatrienoic c-C18:3d6 C18:3o6
- Arachidonic cis-5,8,11,14-eicosatetraenoic c-C20:4d5 C20:4o6
- EPA cis-5,8,11,14,17-eicosapentaenoic c-C20:5d5 C20:5o3
- Erucic cis-13-docosenoic c-C22:1d13 C22:1o9
- DHA cis-4,7,10,13,16,19-docosahexaenoic c-C22:6d4 C22:6o3
-
- EPA and DHA are widely known as the omega-3 fatty acids present in high
- concentrations in marine lipids, and are considered beneficial in diet,
- although research is not complete [4,5].
-
- 12.6 What is Conjugated Linoleic Acid?
-
- Conjugated linoleic acid describes the group of positional and geometric
- isomers of linoleic acid ( cis-9,12-octadecadienoic acid ) that have a
- conjugated double bond system starting at carbon 9, 10, or 11. They can be
- either cis or trans, or various combinations of them. The more abundant
- isomers in food are believed to be the cis-9, trans-11, and the trans-10,
- cis-12 isomers. It's very difficult to separate the cis-9, trans-11 and
- trans-9, cis-11 isomers, however the cis-9, trans-11 form is usually
- considered the important and usually dominant isomer.
-
- They are typically produced by bacteria in the rumen of ruminants because
- the hydrolysis of fats in the rumen produces more unesterified linoleic
- acid than is available to bacteria in other digestive systems. Plants
- also contain conjugated linoleic acid, but there is much less of the
- cis-9, trans-11 isomer, which is believed to be the biologically active
- isomer. Foods that contain CLA are lamb, beef, turkey and dairy fat products,
- ranging from 2.5 - 11 mg/g of fat - of which 75% or more is the cis-9,
- trans-11 ( or trans-9, cis-11 ) isomer. CLA is of interest because it has
- displayed antimutagenic activity in animals and human cell tests [6,7].
-
- 12.7 What are "heavy" metals?
-
- There appears to be no standard definition, however the general consensus
- appears to be all metals with a density greater than 4 or 5 [8,9,10]. If
- you also consider the conventional analytical chemistry definition of "heavy
- metals" ( precipitation of sulfides from acidic solutions ), you obtain
- quite a diverse mixture of possible candidates. Moving the density limit
- from 4 to 5 really only just impacts on Ti, Y and Se. Some other texts use
- more complex definitions that may also include accepted "light" metals with
- densities less than 4, eg Hawley uses "A metal of atomic weight greater
- than sodium (22.9) that forms soaps on reaction with fatty acids. e.g.,
- aluminum, lead, cobalt". The term " heavy-element " is commonly used to
- describe the transfermium elements, - elements with an atomic number
- greater than 100.
-
- 12.8 What is the difference between Molarity and Normality?.
-
- A Molar solution contains one gram molecular weight ( aka mole ) of the
- reagent in one litre of solution, and is represented by " M ". In modern
- usage, "molar" is intended to only mean " divided by amount of substance",
- and is not supposed to be used to describe 1M solutions. There are already
- exceptions to the rule ( molar conductivity, molar extinction coefficient ),
- so I would only worry about correct usage in exams, as in the real world
- most chemists use Molar to describe 1M solutions.
-
- A Molal solution is one gram molecular weight of the reagent in 1 kilogram
- of solvent, and is usually represented by "m". This concentration unit is
- relatively uncommon in the real world, so it's worth checking that the "m"
- is not a "M" typo.
-
- A Normal solution contains one gram equivalent weight ( aka equivalent )
- of the reagent in one litre of solution, and is represented by " N ".
- The equivalent weight of a reagent may vary according to the reaction, but
- if considering just acid and base moles and equivalents, then:-
-
- 1M H2SO4 + 2M NaOH -> 2H2O + Na2SO4
- 1N H2SO4 + 1N NaOH -> H20 + 0.5Na2SO4
- 1N HCl + 1N NaOH -> H2O + NaCl
-
- So you can see that the equivalent weight of an acid is that which contains
- 1.0078 grams of replaceable hydrogen which, in the case of sulfuric acid,
- would be half the mole weight, but, in the case of hydrochloric acid, would
- be the mole weight.
-
- The equivalent weight of a base is that which contains one replaceable
- hydroxyl group ( ie 17.008g of ionisable hydroxyl ). Thus the equivalent
- weight of sodium hydroxide ( NaOH ) and potassium hydroxide ( KOH ) would
- be the mole weight, but for calcium hydroxide ( Ca(OH)2 ) it would be half
- the mole weight.
-
- The equivalent weight of an oxidising or reducing agent is that weight of
- the reagent that reacts with or contains 1.008 grams of available hydrogen
- or 8.000 grams of available oxygen. "Available" means being able to be
- utilised in oxidation or reduction reactions. The equivalent weight of an
- oxidising agent is determined by the change in oxidation number which the
- reduced element experiences, eg the reduction of potassium permanganate in
- dilute H2SO4 gives;-
- K Mn O4 --> Mn S O4
- (Oxidation Number) +1 +7 -8 +2 +6 -8
- This results in a change of the manganese from +7 to +2, so the equivalent
- weight is 1/5 of a mole. However, in neutral solution the change would only
- be 3 because the product is MnO2, giving an equivalent weight of 1/3 of a
- mole. If reacted in strongly alkaline solution the product is MnO4--, giving
- an equivalent weight of one mole.
-
- The equivalent weight of a reducing agent is determined by the change in
- oxidation number that the oxidised element undergoes. For the conversion of
- ferrous sulfate into ferric sulfate;-
- 2 (Fe SO4) --> Fe2 (SO4)3
- (Oxidation Number) 2x(+2 -2 ) (+3)x2 (-2)x3
- The change in oxidation number per atom of iron is 1, so the equivalent
- weight of ferrous sulfate is 1 mole.
-
- There are wide range of rules about the determination of the oxidation
- number, but if you have been taught to use molarity, I would not bother too
- much about normality, as it is mainly used these days by analytical
- chemists - because it is convenient for many common titrations. Analysts
- assume that 1 ml of 1N reagent will react with 1 ml of 1N reagent. However,
- there has been a recent Journal of Chemical Education article that claims
- using normality and equivalent weight does help students understand
- chemistry, but those concepts are unlikely to become widespread again [11].
-
- 12.9 Where can I find the composition of common named reagents?.
-
- Often the best place to start are MSDS sheets or catalogues from commercial
- suppliers. Some textbooks include a list of named reagents and their
- composition that are mentioned in the text. The very common reagents are
- usually also detailed in Hawley or the Merck Index. One chemistry field that
- has a lot of named reagents is analytical chemistry, especially in Thin Layer
- Chromatography, where many of the spray detection reagents have common names.
- Merck produces a handy guide describing the composition and production of
- common TLC spray reagents [12].
-
- Some common reagents include:-
- - aqua regia = 1 part nitric acid and 3 or 4 parts hydrochloric acid.
- - piranha solution = highly dangerous ( explodes on contact with traces of
- organics ), warm (65C), 70:30 mixture of 100% sulfuric acid and 30%
- hydrogen peroxide. It is used, with comprehensive safety precautions,
- in the semiconductor industry, and also in some laboratories to clean
- glassware [13,14,15]. Many chemical laboratories prohibit it, and there
- are much safer, equally effective, alternatives available - refer
- Section 16.7.
-
- ------------------------------
-
- Subject: 13. Illicit and Government Controlled Substances
-
- Contributed by : Yogi Shan
- ## <yshan@nortel.ca>
- [ mutilated by Bruce Hamilton, who agrees with what Yogi has written, but
- has tried to make the FAQ format consistent, and added his opinion. ]
-
- 13.1 What newsgroups/mailing lists discuss illegal drugs?
-
- Current Usenet Newsgroups:
- alt.drugs.* ( 18 different groups including a.d.c )
- alt.drugs.chemistry
- alt.psychoactives
- alt.hemp
- talk.politics.drugs
- alt.rave
- alt.consciousness
- # rec.drugs.announce
- # rec.drugs.cannabis
- rec.drugs.chemistry
- # rec.drugs.misc
- # rec.drugs.psychedelic
- # rec.drugs.smart
-
-
- Mailing lists:
- mdma/ecstasy/"E":
- To subscribe, send mail to listpimp@underground.net with the message:
- SUBSCRIBE mdma <your name>
- psychedelics:
- Leri-L (Leri-L Metaprogramming Mail Service)
- Contact: leri-request@pyramid.com
- TTIL is a moderated mailing list whose purpose is the respectful
- discussion of Psychedelic Religion.
- To subscribe send email to: listproc@phantom.com and put in the body
- of the message: subscribe ttil <your email address>
-
- There are several useful FAQs available in alt.drugs - start there with
- Yogi's Clandestine Chemistry FAQ. Comprehensive overviews of illicit drug
- information available on the Internet are maintained at several sites, eg
- http://hyperreal.com/drugs/
-
- 13.2 Where can I obtain a list of illegal drugs?
-
- From the "Law" Section of the "alt.drugs Clandestine Chemistry Primer/FAQ"
- by Yogi Shan (yshan@nortel.ca), reproduced by permission:
- The drug statutes (possession, conspiracy, and sale), including Schedules
- I to V of the Controlled Substances Act (listing all banned and federally
- regulated drugs and precursors) are in Title 21 [of the United States
- Code] Sections 800-900 (21 USC 800-900).
-
- The US Code is available on the Internet:
- http://www.pls.com:8001/his/usc.html
- http://thorplus.lib.purdue.edu/gpo/
-
- or as gzip compressed files (by Title):
- ftp://etext.archive.umich.edu/pub/Politics/Conspiracy/AJTeel/USC/
-
- A current list of proscribed drugs may be obtained by writing to:
- Drug Enforcement Administration
- Attn: Drug Control Section
- 1405 "I" Street, N.W.
- Washington, D.C. 20537
-
- 13.3 What is the chemical structure of common illegal drugs?
-
- See the Merck Index for the chemical structure of your favourite poison.
- Heilbron ( aka "Dictionary of Organic Compounds ), a multi-volume set,
- is also excellent, and more up to date, though less commonly available.
- Serious structure chasers should also check Beilstein, which often provides
- far more detail of properties and structure than Merck or Heilbron.
-
- 13.4 How do I obtain chemical information on illegal drugs?
-
- Merck, Heilbron and Beilstein all provide information on drugs that have
- a significant presence in the market. Lesser-known homebake and analogues
- are usually not covered, and a search of Chemical Abstracts may not even
- provide information. Because of the various techniques used to "refine"
- and "cut" the active ingredients, most illegal drugs are seldom
- sufficiently pure to match published data. The drugs are marketed on their
- pharmacological and psychological activity, rather than chemical purity
- - similar to vitamin units of activity :-). I suggest you start by reading
- the various alt.drugs FAQs - they all list hardcopy references, and if they
- do not identify an information source, try posting to alt.drugs or rec.drugs.
-
- 13.5 Where are the synthesis instructions for illegal drugs?
-
- By asking the question in sci.chem, you already have signalled your level
- of knowledge of illicit chemistry discussions on Usenet. You should be in
- alt.drugs.* hierarchy and perhaps other groups in section 13.1 :-).
-
- For the short answer, refer to Merck, Heilbron or Beilstein, they will
- provide references to the original synthesis papers. Note that large scale
- production techniques often use procedures that were developed later, and
- street procedures often are significantly different, usually due to
- financial, equipment, or chemical feedstock constraints.
-
- For the long answers, see the "alt.drugs Clandestine Chemistry Primer/FAQ"
- by Yogi Shan (yshan@nortel.ca), and visit some sites listed in the Network
- Resources FAQ available in alt.drugs. For a fairly comprehensive overview,
- ( but no warranty implied for info available there ), you could start at:
- http://hyperreal.com/drugs/
-
- An interesting article on the link between methylenedioxymethamphetamine
- ( MDMA, ecstasy, XTC, Adam ) illegal synthesis and the sassafras tree is
- available [1].
-
- 13.6 Should I post detailed recipes for illegal chemicals?
-
- Well, if you do a lot of people will hate you. On the other hand many people
- will love you. Of course, most people won't care one way or another.
- Or maybe they'll just roll their eyes back, mumble something about
- "dissipated/mis-spent youth", and hit the "next" button.
-
- Posting them to sci.chem means you will be attempting to teach grandmother
- how to suck eggs, most regulars of sci.chem *know* where to find the
- complete instructions, how to perform the synthesis, and have authorised
- access to all the equipment and chemicals. The readers of sci.chem are
- probably not your target audience, and may be a little annoyed that you had
- such a low opinion of their chemistry abilities. If you do not want a
- lot of flames, try posting to the groups in section 13.1, they will probably
- appreciate your contribution more, but will still flame you if it is wrong.
-
- This is Usenet, do what you want as long as you think you can get away with
- it. And don't ever let anyone tell you that you can't. It's a truism on
- Usenet that whatever you do, someone's going to be mad at you. For every
- anarchistic Free Spirit (TM), there's going to be at least one anal-retentive
- busy-body who has nothing better to do that feign outrage at something or
- other. Some idiot in Australia even had the nerve to flame me for posting my
- Clandestine Chemistry FAQ to sci.chem, and I think drugs are terrible, and
- said so. So go figure.
-
- The only caveat to this is that posting mis-information, or information
- that you personally do not understand, is likely to result in a lot of
- flames. If you attempt to post anonymously to sci.chem, it is likely that
- you will encounter far more opposition than if you use your email address.
- As with all of Usenet, posters who sign their names to posts will be held
- accountable for the content, so posting obviously incorrect or incomplete
- syntheses to a group where knowledgeable chemists hang out is more likely to
- harm your credibility. Your posts are unlikely to gain you further knowledge
- of the synthesis, because if you post incorrect details, readers will be
- pointed to the more accurate Clandestine Chemistry FAQ, and also directed to
- the groups in section 13.1 to find the latest details.
-
- In the late 1980s, and early 1990s a poster began to post all the detailed
- synthesis methods from Pihkal to sci.chem. "Pihkal" is Alexander and Ann
- Shulgin's standard text " Phenethylamines I Have Known and Loved [2a]", which
- has recently been supplemented with "Tihkal" ( Tryptamines I have Known and
- Loved ) [2b].
-
- From vague memory, the poster was just listing the recipes, and not entering
- into discussions or responding to questions or comments. There was the usual
- outrage, but I believe he had to stop because of copyright violation of the
- book he was posting - he could not demonstrate to his access provider that
- he had approval from the copyright holder :-). Shulgin has now made Part Two
- of PiKAL freely available, and copies are littered around the Internet, so
- check out the various alt.drugs FAQs for their location.
-
- 13.7 What newsgroups/mailing lists discuss explosives?
-
- Rec.pyrotechnics and alt.engr.explosives are two newsgroups that discuss
- explosives, much to the consternation of some subscribers to the former.
- The rec.pyrotechnics FAQ is excellent, and is posted regularly to
- rec.pyrotechnics, news.answers, and rec.answers.
-
- There's an "Anarchist Cookbook FAQ" posted semi-regularly to rec.pyrotechnics
- and alt.engr.explosives that tells you why the AC is lousy. See also:
- http://www.cwi.nl/cwi/people/Jack.Jansen/spunk/cookbook.html
- This review goes a little overboard: the mercury fulminate and picric
- acid recipes the he refers to are fine by my estimation.
-
- See also [but no warranty implied for info available on]:
- http://paradox1.denver.colorado.edu
- http://www.wiretap.spies.com
-
- 13.8 What is the chemical structure of common explosives?
-
- Exothermic oxidation-reduction reactions are the source of energy, and they
- can be produced from mixtures of discrete fuels and oxidisers, or from
- molecular decomposition - such as from nitroglycerine. Propellants and
- explosives produce large volumes of gases, whereas pyrotechnics do not.
- Gas Reaction Ignition
- Volume Heat Temperature
- (cm3/g) (MJ/KG) (C)
- Photoflash (30:40:30 Ba(NO3)2:Al:KClO4) 15 8.989 700
- TNT 710 4.560 310
-
- Most explosives are organic compounds or mixtures that contain carbon,
- hydrogen, oxygen and nitrogen. Metallic fuels ( eg aluminium ) may be
- added to increase the heat of reaction. Industrial dynamites traditionally
- used nitroglycerine, nitrocellulose, and inorganic salts as sources of
- oxygen, but these have been replaced by formulations that use ammonium
- nitrate as the primary oxygen source. Note that the specific energy is
- usually lower than the combustion of common fuels in air because the fuels
- obtain their oxygen from air.
-
- Many explosive can either burn or detonate, usually depending on the
- type of initiation, confinement, and physical properties of the fuel.
- When initiated, burning first occurs at an increasing rate during the first
- few microseconds as it creates a high velocity, high pressure shock wave
- that exothermically decomposes the explosive as it passes. The wave is
- sustained by the transfer of energy from the reacted explosive to the
- unreacted explosive via shock compression. The reaction rate depends on
- the rate of propagation of the shock wave, rather than the rate of heat
- transfer - as occurs during burning.
-
- Explosives are usually classified into:
- Low Explosives or Propellants
- eg colloidal cellulose nitrate ( smokeless powder ), black powders,
- gun and rocket propellants.
- - they are usually mixtures of chemical compounds that produce large
- volumes of high temperatures gases at controllable rates, and do not
- require atmospheric oxygen. Ammonium perchlorate and ammonium nitrate
- are commonly used as oxidisers.
-
- Initiating or Primary Explosives ( detonators )
- eg lead azide, mercury fulminate, diazodinitrophenol (DDNP).
- - they are used to initiate the next component of an explosive chain, and
- are usually dense, organometallic compounds.
- - these are sensitive materials and fairly dangerous to handle as they
- can be ignited by heat, shock and electrostatic energy.
- Lead Mercury DDNP
- Azide Fulminate
- Density (g/cm3) 4.0 4.2 1.60
- Heat of Combustion (MJ/KG) 2.64 3.93 13.58
- Heat of Detonation (MJ/KG) 1.54 1.79 3.43
- Gas Volume (cm3/g at STP) 308 316 876
- Detonation Velocity (m/s) 5100 5400 6900
-
- High or Secondary Explosives
- There is a distinction between secondary and high, however many of the
- common explosives are considered "secondary high explosives".
- eg cyclotrimethylenetrinitramine (RDX), 2,4,6-trinitrotoluene (TNT),
- cyclotetramethylenetetranitramine (HMX), ammonium picrate (AP).
- "Secondary explosives" include trinitrophenylmethylnitramine (Tetryl),
- nitrocellulose (NC) nitroglycerine (NG), pentaerythritol tetranitrate
- (PETN), and nitromethane. High and secondary explosives require explosive
- shock to initiate their detonation, otherwise they would only burn if
- unconfined or unshocked.
- NG TNT AP RDX HMX Tetryl
- Density (g/cm3) 1.59 1.65 1.72 1.85 1.90 1.70
- Heat of Combustion (MJ/KG) 6.80 15.02 12.09 9.46 9.88 12.24
- Heat of Detonation (MJ/KG) 6.29 4.23 4.31 4.54 5.67 4.63
- Gas Volume (cm3/g) 715 710 680 780 755 760
- Detonation Velocity (m/s) 7600 6940 7050 8570 9160 7920
- Detonation Pressure (GPa) - 18.9 - 33.8 39.3 26.2
-
- RDX and HMX are substantially desensitized when mixed with TNT or coating
- with polymer/elastomer binders. Most RDX in the USA is converted into
- "Composition B" (59.5:39.5:1 RDX:TNT:Wax)
- "A5" (98.5:1.5 RDX:Stearic Acid)
- "C4" (91:5.3:2.1:1.6 RDX:dioctyl sebacate:polyisobutylene:oil).
- Amatol AN
- B 80/20 C4 AN ANFO Slurry
- Density (g/cm3) 1.72 - 1.64 1.72 0.93 1.40
- Heat of Combustion (MJ/KG) 11.67 4.19 - 2.62 - -
- Heat of Detonation (MJ/KG) 5.28 4.10 6.61 2.63 3.76 3.05
- Gas Volume (cm3/g) - 860 - 980 - -
- Detonation Velocity (m/s) 7900 5200 8340 2700 4560 6050
- Detonation Pressure (GPa) 29.5 - 25.7 1.1 6.0 10.4
-
- Note that explosives usually have less potential energy than gasoline, but
- it is the high rate of energy release that produces the blast pressure.
- TNT has a detonation velocity of 6,940 m/s compared to 1,680 m/s for the
- detonation of pentane in air, and the 0.34 m/s stoichiometric flame speed
- of gasoline combustion in air.
-
- Other than ammonium nitrate/fuel oil (ANFO), most common explosives are
- trinitrated organic compounds. Nitroglycerine (glyceryl nitrate),
- trinitrotoluene (TNT), picric acid, C4 (plasticized RDX/Cyclonite),
- and tetryl (2,4,6-trinitrophenylmethylnitramine), fall into this category.
- Refer to Merck or Kirk Othmer for chemical structures of common explosives.
-
- A range of Semtex plastic explosives were produced by the Semtin Glassworks
- in Czechoslovakia ( now known as VCHZ Synthesia ). Semtex-H is commonly used
- by terrorists and, although examples are of variable composition, it
- typically contains approximately 8% oil, 9% rubber, and approximately equal
- quantities of RDX and PETN, but with known composition ranges of >21.5% RDX
- and <64.5% of PETN. [3,4].
-
- ANFO was proposed in 1867, but it was the development of anti-caking agents
- in the 1950s that made ANFO suitable for rock blasting. Typical commercial
- ANFO blasting agents consist of 94% ammonium nitrate prills (coated with an
- anti-caking agent) and 6% fuel oil. They are reclassified as blasting
- explosives if the formulation is sensitised by the addition of high
- explosive. ANFO explosives are usually initiated by a high-explosive booster
- such as formulation B. Maximum sensitivity to initiation occurs around 2-4%
- fuel oil, with the presence of water decreasing sensitivity. The recent bomb
- in Oklahoma City (estimated 1800kg ANFO)[5], demonstrated the destructive
- capacity of ANFO explosives.
-
- There were solubility problems using ANFO in wet drill holes, so aqueous-
- based slurries were developed. These are usually thickened suspensions
- dispersed in a saturated salt solution that has been made water resistant
- by the addition of hydrophilic colloids that inhibit water migration.
- Ammonium nitrate-based explosives account for 97% of the US industrial
- explosives.
-
- The infamous nitrogen tri-iodide ( touch powder ) produced by the reaction
- of ammonia with iodine, is not actually NI3, but a nitrogen iodide/ammonia
- complex with the structure NI3(NH3)n where n = 1, 3, or 5 - depending on
- conditions. NI3 has only recently been isolated, and is stable at -196C,
- decomposes slowly at -78C, and decomposes spontaneously at 0C [6]. Refer to
- an older inorganic chemistry text, such as "The Chemical Elements and their
- Compounds"[7], for further details and references.
-
- Recently, there has been great interest in the development of more energetic
- materials, and several new compounds are expected to replace existing
- materials - once manufacturing costs are reduced. Examples include;- ADN
- (Ammonium Dinitramide - NH4N(NO2)2, used as a propellant by the Soviet Union),
- CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexazaisowurtzitane, aka HNIW,
- the most powerful single-component explosive known - which, when combined
- with a polymer binder is also known as LX19), and TNAZ
- (1,3,3-trinitroazetidine) [8,9,10].
-
- 13.9 How do I obtain chemical information on common explosives?
-
- There is an excellent, well-referenced "Explosives and Propellants" monograph
- in Kirk Othmer [11] and there are also the popular books "Explosives" by Meyer
- [12], and "Chemistry of Powder and Explosives" by Davis [13]. Many of the
- relevant properties of fuels and explosives are found in an easily-accessible
- Bureau of Mines report "Investigations of Fire and Explosion Accidents in the
- Chemical, Mining, and Fuel-Related Industries - A Manual" by J.M.Kuchta [14].
- There is also the "Propellants, Explosives and Pyrotechnics" journal. Merck
- lists most common, and many uncommon explosives, giving their structure,
- selected properties, and pointers to synthesis and more detailed information.
- Shreve and Kirk Othmer also discuss explosives manufacture.
-
- Tadeusz Urbanski wrote a massive four-volume reference set on explosives
- "The Chemistry and Technology of Explosives" [15] that should be available
- in any university science library (it's something like US$700 otherwise).
-
- The "Encyclopedia of Explosives and Related Items", aka "PATR 2700"
- (Picatinny Arsenal Technical Report) [16], is a U.S. Army (Picatinny
- Arsenal, Dover, NJ), all-encompassing compilation (10 volumes) of
- explosives properties and chemistry. Like Urbanski, it's also quite
- expensive.
-
- 13.10 What newsgroups/mailing lists discuss pyrotechnics?
-
- rec.pyrotechnics is the "official" newsgroup for fireworks/pyrotechnics
- discussions, though many have fled to the mailing lists due to the large
- numbers of juvenile "mad bomber" type posts that abound.
-
- Mark A. Buda < buda@star.enet.dec.com >
- The original rec.pyro exile fireworks list.
- "Mad Bomber" posts forbidden.
- The Pyro Mailing List is a "Real" pyrotechnic discussion group moderated by
- a pyrotechnician. No mad bombers.
- To subscribe apply to pml@vnet.net and follow the instructions.
- One must supply the info and there are reasonable guidelines to follow.
- Murr Rhame <murr@jazzmin.vnet.net>
- Show-Fire entertainment pyrotechnics mailing list.
- "Mad Bomber" posts forbidden.
- To subscribe send the following one line message to listserv@vnet.net:
- subscribe show-fire name@your.address
- Ken Harthun <omckenh@pipeline.com>
- PyroTechniques, The Newsletter for Pyrotechnic Enthusiasts. It is FREE
- for the asking. Just email me with a request to be added to the list.
-
- See also:
- http://mercury.aichem.arizona.edu/~tip/pyro.html
- http://nickel.ucs.indiana.edu/~flinn/pyro/pyro.html
- http://fireworks.com/
-
- ------------------------------
-
- Subject: 14. Academic Course Information
-
- 14.1 Where do I find information on US courses?
-
- The advent of the WWW has meant that many educational institutions now have
- their courses listed. A WWW search should reveal the address of most
- institutions, and several of the more popular chemical courses are linked to
- some of the general chemistry education sites listed in section 7.2.
- Note that most US educational institutions will have a *.edu (education)
- Internet address. Also check out the various Chemical Society homepages.
-
- 14.2 Where do I find information on other nations' courses?
-
- Once again, try using the WWW, as many educational institutions worldwide
- are placing course information on their home pages. It is worth remembering
- that not all countries use *.edu (education), as the educational institution
- address, some countries use *.ac (academic) eg vuw.ac.nz is Victoria
- University in Wellington, New Zealand.
-
- ------------------------------
-