You can open the Wizard by going to : Profile / Add with Wizard
The following screen will pop up.
IMPORTANT!
The wizards title bar will give some information on what you're supposed to do. Take note of [Template : Default] this indicates that you're adding a profile using the Default Configuration. If you were using a Template or you configured a different Default Template Default would have been replaced by a template name of your own. Read more on templates in this chapter.
To continue creating a profile press the '>>' button and follow the instruction. When the '>>' button turns into Finish you've completed creating the profile. Press the Finish button and your profile is done.
Note that the '>>' button will be disabled if you entered invalid data. For example, the wizard will not let you procedure until you've selected a valid game exe.