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1994-07-22
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ARRoGANT CoURiERS WiTH ESSaYS
Grade Level: Type of Work Subject/Topic is on:
[ ]6-8 [ ]Class Notes [An essay on the causes ]
[x]9-10 [ ]Cliff Notes [and effects of acid rain]
[ ]11-12 [x]Essay/Report [9 pgs. ]
[ ]College [ ]Misc [ ]
Dizzed: 07/94 # of Words:2000 School: ? State: ?
─────────>─────────>─────────>Chop Here>─────────>─────────>─────────>─────────
INTRODUCTION: Acid rain is a great problem in our world. It causes
fish and plants to die in our waters. As well it causes harm to our
own race as well, because we eat these fish, drink this water and
eat these plants. It is a problem that we must all face together
and try to get rid of. However acid rain on it's own is not the
biggest problem. It cause many other problems such as aluminum
poisoning. Acid Rain is deadly.
WHAT IS ACID RAIN?
Acid rain is all the rain, snow, mist etc that falls from
the sky onto our planet that contains an unnatural acidic. It
is not to be confused with uncontaminated rain that falls, for
that rain is naturally slightly acidic. It is caused by today's
industry. When products are manufactured many chemicals are
used to create it. However because of the difficulty and cost
of properly disposing of these products they are often emitted
into the atmosphere with little or no treatment.
The term was first considered to be important about 20
years ago when scientists in Sweden and Norway first believed
that acidic rain may be causing great ecological damage to the
planet. The problem was that by the time that the scientist
found the problem it was already very large. Detecting an acid
lake is often quite difficult. A lake does not become acid
over night. It happens over a period of many years, some times
decades. The changes are usually to gradual for them to be
noticed early.
At the beginning of the 20th century most rivers/lakes
like the river Tovdal in Norway had not yet begun to die.
However by 1926 local inspectors were noticing that many of the
lakes were beginning to show signs of death. Fish were found
dead along the banks of many rivers. As the winters ice began
to melt off more and more hundreds upon hundreds more dead fish
(trout in particular) were being found. It was at this time
that scientist began to search for the reason. As the
scientists continued to work they found many piles of dead
fish, up to 5000 in one pile, further up the river. Divers were
sent in to examine the bottom of the rivers. What they found
were many more dead fish. Many live and dead specimens were
taken back to labs across Norway. When the live specimens were
examined they were found to have very little sodium in their
blood. This is typical a typical symptom of acid poisoning. The
acid had entered the gills of the fish and poisoned them so
that they were unable to extract salt from the water to
maintain their bodies sodium levels.
Many scientist said that this acid poising was due to the
fact that it was just after the winter and that all the snow
and ice was running down into the streams and lakes. They
believed that the snow had been exposed to many natural
phenomena that gave the snow it's high acid content. Other
scientists were not sure that this theory was correct because
at the time that the snow was added to the lakes and streams
the Ph levels would change from around 5.2 to 4.6. They
believed that such a high jump could not be attributed to
natural causes. They believed that it was due to air pollution.
They were right. Since the beginning of the Industrial
revolution in England pollution had been affecting all the
trees,soil and rivers in Europe and North America.
However until recently the loses of fish was contained to
the southern parts of Europe. Because of the constant onslaught
of acid rain lakes and rivers began to lose their ability to
counter act their affects. Much of the alkaline elements; such
as calcium and limestone; in the soil had been
washed away. It is these lakes that we must be worried about
for they will soon become extinct.
A fact that may please fishermen is that in lakes/rivers
they tend to catch older and larger fish. This may please them
in the short run however they will soon have to change lakes
for the fish supply will die quickly in these lakes. The
problem is that acid causes difficulties the fish's
reproductive system. Often fish born in acid lakes do not
survive for they are born with birth defects such as twisted
and deformed spinal columns. This is a sign that they are
unable to extract enough calcium from the water to fully
develop their bone. These young soon die. With no competition
the older,stronger can grow easily. However there food is
contaminated as well by the acid in the water. Soon they have
not enough food for themselves and turn to cannibalism. With
only an older population left there is no one left to
regenerate themselves. Soon the lake dies.
By the late 1970s many Norwegian scientists began to
suspect that it was not only the acid in the water that was
causing the deaths. They had proved that most fish could
survive in a stream that had up to a 1 unit difference in PH.
After many experiments and research they found that their
missing link was aluminum.
Aluminum is one of the most common metals on earth. It is
stored in a combined form with other elements in the earth.
When it is combined it cannot dissolve into the water and harm
the fish and plants. However the acid from acid rain can easily
dissolve the bond between these elements. The Aluminum is then
dissolved into a more soluble state by the acid. Other metals
such as Copper (Cu), iron (Fe) etc can cause such effects upon
the fish as well however it is the aluminum that is the most
common.
For example: CuO + H2SO4 ----------> CuSO4 + H2O
In this form it is easily absorbed into the water. When it
comes in contact with fish it causes irritation to the gills.
In response the fish creates a film of mucus in the gills to
stop this irritation until the irritant is gone. However the
aluminum does not go always and the fish continues to build up
more and more mucus to counteract it. Eventually there is so
much mucus that it clogs the gills. When this happens the fish
can no longer breath. It dies and then sinks to the bottom of
the lake. Scientists now see acid, aluminum and shortages of
calcium as the three determining factors in the extinction of
fish.
As well there is the problem of chlorine. In many parts of
the world it is commonly found in the soil. If it enters the
fish's environment it can be deadly. It affects many of the
fish's organisms and causes it to die. As well it interferes in
the photosynthesis process in plants.
NaOH + HCl ----> NaCl + H2O
The carbon in the water can become very dangerous for fish and
plants in the water if the following reaction happens:
CaCO3 + 2HCl ---> CaCl2 + H2CO3 then
H2CO3 ---> H2O + CO2
The salt created by this reaction can kill. It interferes
directly with the fish's nervous system.
Acid lakes are deceivingly beautiful. The are crystal
clear and have a luscious carpet of green algae on the bottom.
The reason that these lakes are so clear is because many of the
decomposers are dead. They cannot break down that material such
as leaves and dead animals. These materials eventually sink to
the bottom instead of going through the natural process of
decomposition. In acid lakes decomposition is very slow. "The
whole metabolism of the lake is slowed down."
During this same period of time the Canadian department of
fisheries spent eight years dumping sulfuric acid (H2SO4) into
an Ontario lake to see the effects of the decrease in the PH
over a number of years. At the PH of 5.9 the first organisms
began to disappear. They were shrimps. They started out at a
population of about seven million, but at the pH of 5.9 they
were totally wiped out. Within a year the minnow died because
it could no longer reproduce it's self.
At this time the pH was of 5.8. New trout were failing to
be produced because many smaller organisms that served as food
to it had been wiped out earlier. With not enough food the
older fish did not have the energy to reproduce. Upon reaching
the pH of 5.1 it was noted that the trout became cannibals. It
is believed this is due to the fact that the minnow was nearly
extinct.
At a pH of 5.6 the external skeletons of crayfish softened
and they were soon infected with parasites, and there eggs were
destroyed by fungi. When the pH went down to 5.1 they were
almost gone. By the end of the experiment none of the major
species had survived the trials of the acid. The next
experiment conducted by the scientists was to try and bring the
lake back to life. They cut in half the amount of acid that
they dumped to simulate a large scale cleanup. Soon again the
cuckers and minnows began to reproduce again. The lake
eventually did come back; to a certain extent; back to life.
THE NEW THEORY:
A scientist in Norway had a problem believing that it was
the acid rain on it's own that was affecting the lakes in such
a deadly way. This scientist was Dr Rosenqvist.
"Why is it that during heavy rain, the swollen rivers can be up
to fifteen times more acid than the rain? It cannot be the rain
alone that is doing it, can it?" Many scientist shunned him
for this however they could not come up with a better answer.
Soon the scientists were forced to accept this theory.
Sulfuric acid is composed of two parts, know as ions. The
hydrogen ion is what make a substance acid. The other ion is
sulphate. When there are more hydrogen ions then a substance is
acid. It is this sulphate ion that we are interested in. When
the rain causes rivers to overboard onto the banks the river
water passes through the soil. Since the industrial revolution
in britain there has been an increasing amount of sulphur in
the soil. In the river there is not enough sulphur for the acid
to react in great quantities. However in the soil there is a
great collection of sulphur to aid the reaction. When it joins
the water the pH becomes much lower. This is the most deadly
effect of acid rain on our water!!! The water itself does not
contain enough sulphur to kill off it's population of fish and
plants. But with the sulphur in the soil it does.
CONCLUSION:
Acid rain is a big problem. It causes the death of our lakes,
our rivers, our wild life and most importantly us. As well it
causes other problems that are very serious as well such as the
release of aluminium and lead into our water supplies. We are
suffering because of it. In Scotland there are many birth
defects being attributed to it. We must cut down the releases
of chemicals that cause it. But it will take time, even if we
were to stop today we would have the problem for years to come
because of the build up in the soil. Let's hope we can do
something.
BIBLIOGRAPHY
Penguin Publishing House, 1987 , Pearce Fred Acid Rain. What is
it and what is it doing to us?
New York Publishers, 1989, William Stone Acid Rain. Fiend or
Foe?
Lucent books, Inc. 1990, Steward Gail Acid Rain.